| 1. Round | 18/09/2022 | 1. FC Köln [Women] | - | 1899 Hoffenheim [Women] | 3:1 | ||||
| 2. Round | 23/09/2022 | Bayer Leverkusen [Women] | - | 1. FC Köln [Women] | 1:0 | ||||
| 3. Round | 01/10/2022 | 1. FC Köln [Women] | - | Turbine Potsdam [Women] | 4:2 | ||||
| 5. Round | 23/10/2022 | 1. FC Köln [Women] | - | Werder Bremen [Women] | 2:0 | ||||
| 6. Round | 28/10/2022 | MSV Duisburg [Women] | - | 1. FC Köln [Women] | 2:1 | ||||
| 7. Round | 06/11/2022 | Eintracht Frankfurt [Women] | - | 1. FC Köln [Women] | 2:0 | ||||
| 8. Round | 27/11/2022 | 1. FC Köln [Women] | - | VfL Wolfsburg [Women] | 0:4 | ||||
| 9. Round | 04/12/2022 | SV Meppen [Women] | - | 1. FC Köln [Women] | 1:0 | ||||
| 10. Round | 11/12/2022 | 1. FC Köln [Women] | - | SC Freiburg [Women] | 0:0 | ||||
| 11. Round | 03/02/2023 | SGS Essen [Women] | - | 1. FC Köln [Women] | 4:0 | ||||
| 12. Round | 12/02/2023 | 1899 Hoffenheim [Women] | - | 1. FC Köln [Women] | 4:0 |  |
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| 20. Round | 14/05/2023 | 1. FC Köln [Women] | - | SV Meppen [Women] | 1:2 | |
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| 21. Round | 21/05/2023 | SC Freiburg [Women] | - | 1. FC Köln [Women] | 1:3 |
Germany