| 3. Round | 20/08/2022 | VfB Stuttgart | - | SC Freiburg | 0:1 | ||||
| 4. Round | 26/08/2022 | SC Freiburg | - | VfL Bochum | 1:0 | ||||
| 5. Round | 03/09/2022 | Bayer Leverkusen | - | SC Freiburg | 2:3 | ||||
| 16. Round | 21/01/2023 | VfL Wolfsburg | - | SC Freiburg | 6:0 | ||||
| 18. Round | 28/01/2023 | SC Freiburg | - | FC Augsburg | 3:1 | ||||
| 19. Round | 04/02/2023 | Borussia Dortmund | - | SC Freiburg | 5:1 | ||||
| 20. Round | 11/02/2023 | SC Freiburg | - | VfB Stuttgart | 2:1 | ||||
| 23. Round | 04/03/2023 | Bor. Mönchengladbach | - | SC Freiburg | 0:0 | ||||
| 24. Round | 12/03/2023 | SC Freiburg | - | 1899 Hoffenheim | 2:1 | ||||
| 25. Round | 19/03/2023 | 1. FSV Mainz 05 | - | SC Freiburg | 1:1 |  |
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| 26. Round | 01/04/2023 | SC Freiburg | - | Hertha BSC | 1:1 | |
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| 27. Round | 08/04/2023 | SC Freiburg | - | Bayern München | 0:1 | ||||
| 31. Round | 06/05/2023 | SC Freiburg | - | RB Leipzig | 0:1 | ||||
| 32. Round | 13/05/2023 | 1. FC Union Berlin | - | SC Freiburg | 4:2 |  |
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| 34. Round | 27/05/2023 | Eintracht Frankfurt | - | SC Freiburg | 2:1 |
Germany