| 2. Round | 06/08/2022 | TSV Schott Mainz | - | TuS Koblenz | 2:1 | ||||
| 9. Round | 24/09/2022 | TSV Schott Mainz | - | TuS Kirchberg | 7:0 | ||||
| 10. Round | 01/10/2022 | TSG Pfeddersheim | - | TSV Schott Mainz | 1:3 | ||||
| 13. Round | 22/10/2022 | TuS Koblenz | - | TSV Schott Mainz | 0:0 | ||||
| 14. Round | 29/10/2022 | TSV Schott Mainz | - | SG Mülheim-Kärlich | 2:0 | ||||
| 15. Round | 05/11/2022 | SV Alemannia Waldalgesheim | - | TSV Schott Mainz | 0:3 | ||||
| 16. Round | 12/11/2022 | TSV Schott Mainz | - | Ahrweiler BC | 4:1 | ||||
| 11. Round | 16/11/2022 | TSV Schott Mainz | - | FV Engers 07 | 2:4 | ||||
| 18. Round | 26/11/2022 | Sportfreunde Eisbachtal | - | TSV Schott Mainz | 1:4 | ||||
| 19. Round | 03/12/2022 | TSV Schott Mainz | - | FC Karbach | 1:0 | ||||
| 20. Round | 10/12/2022 | TuS Kirchberg | - | TSV Schott Mainz | 1:4 |
Germany