| 2. Round | 17/08/2013 | VfL Wolfsburg | - | FC Schalke 04 | 4:0 | ||||
| 4. Round | 31/08/2013 | FC Schalke 04 | - | Bayer Leverkusen | 2:0 |  |
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| 5. Round | 14/09/2013 | 1. FSV Mainz 05 | - | FC Schalke 04 | 0:1 | ||||
| 6. Round | 21/09/2013 | FC Schalke 04 | - | Bayern München | 0:4 | ||||
| 7. Round | 28/09/2013 | 1899 Hoffenheim | - | FC Schalke 04 | 3:3 | |
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| 8. Round | 05/10/2013 | FC Schalke 04 | - | FC Augsburg | 4:1 | ||||
| 9. Round | 19/10/2013 | Eintracht Braunschweig | - | FC Schalke 04 | 2:3 | ||||
| 33. Round | 03/05/2014 | SC Freiburg | - | FC Schalke 04 | 0:2 |
Germany
