| 12. Round | 28/09/1990 | MSV Duisburg | - | Hannover 96 | 4:2 | ||||
| 13. Round | 07/10/1990 | SC Freiburg | - | MSV Duisburg | 0:2 | ||||
| 14. Round | 12/10/1990 | MSV Duisburg | - | 1. FSV Mainz 05 | 2:0 | ||||
| 15. Round | 19/10/1990 | Fortuna Köln | - | MSV Duisburg | 2:2 | ||||
| 16. Round | 26/10/1990 | MSV Duisburg | - | Rot-Weiss Essen | 4:2 |  |
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| 17. Round | 10/11/1990 | SV Darmstadt 98 | - | MSV Duisburg | 2:2 | ||||
| 18. Round | 16/11/1990 | MSV Duisburg | - | 1. FC Saarbrücken | 1:0 | ||||
| 28. Round | 06/04/1991 | MSV Duisburg | - | FC 08 Homburg | 4:0 | ||||
| 31. Round | 20/04/1991 | Hannover 96 | - | MSV Duisburg | 2:0 | ||||
| 32. Round | 03/05/1991 | MSV Duisburg | - | SC Freiburg | 1:0 | ||||
| 36. Round | 31/05/1991 | MSV Duisburg | - | SV Darmstadt 98 | 2:0 | ||||
| 37. Round | 09/06/1991 | 1. FC Saarbrücken | - | MSV Duisburg | 0:1 | ||||
| 38. Round | 16/06/1991 | MSV Duisburg | - | Blau-Weiß 90 Berlin | 1:0 |
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