| 3. Round | 10/08/2013 | SC Paderborn 07 | - | 1. FC Köln | 1:1 | ||||
| 4. Round | 17/08/2013 | 1. FC Köln | - | SV Sandhausen | 2:0 | ||||
| 12. Round | 25/10/2013 | Arminia Bielefeld | - | 1. FC Köln | 0:1 |  |
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| 13. Round | 04/11/2013 | 1. FC Köln | - | 1. FC Union Berlin | 4:0 | ||||
| 34. Round | 11/05/2014 | FSV Frankfurt | - | 1. FC Köln | 2:0 |
Germany