1. Round | 06/08/2022 | VfL Bochum | - | 1. FSV Mainz 05 | 1:2 | ||||
2. Round | 14/08/2022 | 1. FSV Mainz 05 | - | 1. FC Union Berlin | 0:0 | ||||
3. Round | 20/08/2022 | FC Augsburg | - | 1. FSV Mainz 05 | 1:2 | ||||
4. Round | 27/08/2022 | 1. FSV Mainz 05 | - | Bayer Leverkusen | 0:3 | ||||
5. Round | 04/09/2022 | Bor. Mönchengladbach | - | 1. FSV Mainz 05 | 0:1 | ||||
6. Round | 10/09/2022 | 1899 Hoffenheim | - | 1. FSV Mainz 05 | 4:1 | ||||
7. Round | 16/09/2022 | 1. FSV Mainz 05 | - | Hertha BSC | 1:1 | ||||
18. Round | 28/01/2023 | 1. FSV Mainz 05 | - | VfL Bochum | 5:2 | ||||
19. Round | 04/02/2023 | 1. FC Union Berlin | - | 1. FSV Mainz 05 | 2:1 |