| 2. Round | 13/08/2022 | Hertha BSC | - | Eintracht Frankfurt | 1:1 |  |
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| 3. Round | 19/08/2022 | Bor. Mönchengladbach | - | Hertha BSC | 1:0 | ||||
| 7. Round | 16/09/2022 | 1. FSV Mainz 05 | - | Hertha BSC | 1:1 | ||||
| 8. Round | 02/10/2022 | Hertha BSC | - | 1899 Hoffenheim | 1:1 | ||||
| 10. Round | 15/10/2022 | RB Leipzig | - | Hertha BSC | 3:2 | ||||
| 13. Round | 05/11/2022 | Hertha BSC | - | Bayern München | 2:3 | ||||
| 15. Round | 12/11/2022 | Hertha BSC | - | 1. FC Köln | 2:0 | ||||
| 16. Round | 21/01/2023 | VfL Bochum | - | Hertha BSC | 3:1 | ||||
| 17. Round | 24/01/2023 | Hertha BSC | - | VfL Wolfsburg | 0:5 | ||||
| 19. Round | 04/02/2023 | Eintracht Frankfurt | - | Hertha BSC | 3:0 | |
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| 20. Round | 12/02/2023 | Hertha BSC | - | Bor. Mönchengladbach | 4:1 | ||||
| 22. Round | 25/02/2023 | Hertha BSC | - | FC Augsburg | 2:0 | ||||
| 25. Round | 18/03/2023 | 1899 Hoffenheim | - | Hertha BSC | 3:1 | |
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| 30. Round | 30/04/2023 | Bayern München | - | Hertha BSC | 2:0 | ||||
| 31. Round | 06/05/2023 | Hertha BSC | - | VfB Stuttgart | 2:1 | ||||
| 32. Round | 12/05/2023 | 1. FC Köln | - | Hertha BSC | 5:2 | |
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| 33. Round | 20/05/2023 | Hertha BSC | - | VfL Bochum | 1:1 | |
Germany