| 2. Round | 10/08/1966 | 1. FC Union Berlin | - | HFC Chemie | 0:0 | ||||
| 14. Round | 18/02/1967 | 1. FC Union Berlin | - | Hansa Rostock | 3:0 |  |
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| 15. Round | 25/02/1967 | HFC Chemie | - | 1. FC Union Berlin | 2:1 | ||||
| 16. Round | 04/03/1967 | 1. FC Union Berlin | - | FC Carl Zeiss Jena | 1:1 | ||||
| 18. Round | 15/03/1967 | 1. FC Union Berlin | - | BSG Chemie Leipzig | 0:3 | ||||
| 19. Round | 08/04/1967 | 1. FC Lokomotive Leipzig | - | 1. FC Union Berlin | 0:3 | ||||
| 20. Round | 15/04/1967 | 1. FC Union Berlin | - | BSG Wismut Gera | 1:0 | ||||
| 21. Round | 22/04/1967 | FC Karl-Marx-Stadt | - | 1. FC Union Berlin | 2:2 | |
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| 22. Round | 26/04/1967 | 1. FC Union Berlin | - | BFC Dynamo | 3:0 | ||||
| 23. Round | 04/05/1967 | FC Vorwärts Berlin | - | 1. FC Union Berlin | 1:0 | ||||
| 24. Round | 07/05/1967 | 1. FC Union Berlin | - | BSG Wismut Aue | 0:3 | ||||
| 26. Round | 13/05/1967 | 1. FC Union Berlin | - | BSG Lokomotive Stendal | 3:1 | |
Germany