| 1. Round | 29/08/1999 | Sportfreunde Siegen [Women] | - | WSV Wolfsburg-Wendschott [Women] | 1:1 |  |
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| 2. Round | 05/09/1999 | Turbine Potsdam [Women] | - | Sportfreunde Siegen [Women] | 4:2 | ||||
| 3. Round | 12/09/1999 | Sportfreunde Siegen [Women] | - | TuS Niederkirchen [Women] | 5:2 | |
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| 4. Round | 19/09/1999 | Grün-Weiß Brauweiler [Women] | - | Sportfreunde Siegen [Women] | 4:2 | ||||
| 5. Round | 03/10/1999 | Sportfreunde Siegen [Women] | - | FSV Frankfurt [Women] | 3:0 | ||||
| 13. Round | 24/04/2000 | Sportfreunde Siegen [Women] | - | Turbine Potsdam [Women] | 1:0 | ||||
| 21. Round | 14/05/2000 | 1. FFC Frankfurt [Women] | - | Sportfreunde Siegen [Women] | 3:0 | ||||
| 22. Round | 21/05/2000 | Sportfreunde Siegen [Women] | - | 1. FC Saarbrücken [Women] | 2:0 |
Germany