| 3. Round | 24/08/2013 | 1899 Hoffenheim | - | SC Freiburg | 3:3 | ||||
| 4. Round | 27/08/2013 | SC Freiburg | - | Bayern München | 1:1 |  |
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| 5. Round | 14/09/2013 | FC Augsburg | - | SC Freiburg | 2:1 | |
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| 7. Round | 28/09/2013 | Borussia Dortmund | - | SC Freiburg | 5:0 | ||||
| 8. Round | 06/10/2013 | SC Freiburg | - | Eintracht Frankfurt | 1:1 | |
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| 9. Round | 19/10/2013 | Werder Bremen | - | SC Freiburg | 0:0 | |
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| 11. Round | 02/11/2013 | 1. FC Nürnberg | - | SC Freiburg | 0:3 | ||||
| 12. Round | 10/11/2013 | SC Freiburg | - | VfB Stuttgart | 1:3 | ||||
| 13. Round | 23/11/2013 | Eintracht Braunschweig | - | SC Freiburg | 0:1 | ||||
| 14. Round | 01/12/2013 | Bor. Mönchengladbach | - | SC Freiburg | 1:0 | ||||
| 15. Round | 08/12/2013 | SC Freiburg | - | VfL Wolfsburg | 0:3 | ||||
| 16. Round | 15/12/2013 | FC Schalke 04 | - | SC Freiburg | 2:0 | |
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| 31. Round | 19/04/2014 | SC Freiburg | - | Bor. Mönchengladbach | 4:2 | ||||
| 32. Round | 26/04/2014 | VfL Wolfsburg | - | SC Freiburg | 2:2 |
Germany