| 1. Round | 08/09/2013 | TuS Wörrstadt [Women] | - | 1. FC Köln [Women] | 0:8 |  |
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| 2. Round | 15/09/2013 | 1. FC Köln [Women] | - | SC 07 Bad Neuenahr [Women] | 3:0 | ||||
| 3. Round | 06/10/2013 | SV 67 Weinberg [Women] | - | 1. FC Köln [Women] | 2:3 | ||||
| 4. Round | 13/10/2013 | 1. FC Köln [Women] | - | 1. FFC 08 Niederkirchen [Women] | 3:0 | ||||
| 5. Round | 20/10/2013 | 1. FFC Frankfurt II [Women] | - | 1. FC Köln [Women] | 0:4 | ||||
| 6. Round | 27/10/2013 | 1. FC Köln [Women] | - | VfL Bochum [Women] | 2:1 | ||||
| 9. Round | 24/11/2013 | ETSV Würzburg [Women] | - | 1. FC Köln [Women] | 1:2 | ||||
| 12. Round | 23/02/2014 | 1. FC Köln [Women] | - | TuS Wörrstadt [Women] | 4:0 | |
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| 14. Round | 16/03/2014 | 1. FC Köln [Women] | - | SV 67 Weinberg [Women] | 4:2 |  |
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| 19. Round | 04/05/2014 | TSV Crailsheim [Women] | - | 1. FC Köln [Women] | 2:1 |
Germany