| 7. Round | 28/09/2013 | Borussia Dortmund | - | SC Freiburg | 5:0 | ||||
| 24. Round | 09/03/2014 | SC Freiburg | - | Borussia Dortmund | 0:1 | ||||
| 26. Round | 22/03/2014 | Hannover 96 | - | Borussia Dortmund | 0:3 | ||||
| 28. Round | 29/03/2014 | VfB Stuttgart | - | Borussia Dortmund | 2:3 |  |
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| 29. Round | 05/04/2014 | Borussia Dortmund | - | VfL Wolfsburg | 2:1 | ||||
| 31. Round | 19/04/2014 | Borussia Dortmund | - | 1. FSV Mainz 05 | 4:2 | ||||
| 32. Round | 26/04/2014 | Bayer Leverkusen | - | Borussia Dortmund | 2:2 |  |
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| 34. Round | 10/05/2014 | Hertha BSC | - | Borussia Dortmund | 0:4 |
Germany
