| 3. Round | 21/08/1993 | MSV Duisburg | - | VfB Stuttgart | 2:2 | ||||
| 5. Round | 31/08/1993 | Werder Bremen | - | MSV Duisburg | 1:5 | ||||
| 12. Round | 15/10/1993 | MSV Duisburg | - | Eintracht Frankfurt | 1:0 | ||||
| 13. Round | 22/10/1993 | 1. FC Kaiserslautern | - | MSV Duisburg | 2:0 | ||||
| 14. Round | 30/10/1993 | MSV Duisburg | - | 1. FC Nürnberg | 1:0 | ||||
| 15. Round | 06/11/1993 | Karlsruher SC | - | MSV Duisburg | 5:0 | ||||
| 19. Round | 05/12/1993 | MSV Duisburg | - | Dynamo Dresden | 1:1 | ||||
| 21. Round | 12/02/1994 | MSV Duisburg | - | VfB Leipzig | 2:1 | ||||
| 22. Round | 18/02/1994 | MSV Duisburg | - | Werder Bremen | 1:0 | ||||
| 23. Round | 26/02/1994 | Bayern München | - | MSV Duisburg | 4:0 | ||||
| 24. Round | 04/03/1994 | MSV Duisburg | - | SG Wattenscheid 09 | 2:1 |  |
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| 25. Round | 11/03/1994 | Borussia Dortmund | - | MSV Duisburg | 2:1 | ||||
| 26. Round | 18/03/1994 | MSV Duisburg | - | Hamburger SV | 0:1 | ||||
| 27. Round | 26/03/1994 | 1. FC Köln | - | MSV Duisburg | 1:0 | ||||
| 28. Round | 31/03/1994 | MSV Duisburg | - | Bor. Mönchengladbach | 2:0 | ||||
| 31. Round | 16/04/1994 | 1. FC Nürnberg | - | MSV Duisburg | 0:0 | ||||
| 33. Round | 30/04/1994 | FC Schalke 04 | - | MSV Duisburg | 1:3 | ||||
| 34. Round | 07/05/1994 | MSV Duisburg | - | SC Freiburg | 0:2 |
Germany