| 3. Round | 16/09/2012 | SC Freiburg | - | 1899 Hoffenheim | 5:3 |  |
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| 7. Round | 06/10/2012 | Bayern München | - | 1899 Hoffenheim | 2:0 | ||||
| 17. Round | 16/12/2012 | 1899 Hoffenheim | - | Borussia Dortmund | 1:3 | ||||
| 19. Round | 26/01/2013 | Eintracht Frankfurt | - | 1899 Hoffenheim | 2:1 | |
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| 20. Round | 02/02/2013 | 1899 Hoffenheim | - | SC Freiburg | 2:1 | ||||
| 24. Round | 03/03/2013 | 1899 Hoffenheim | - | Bayern München | 0:1 | ||||
| 25. Round | 09/03/2013 | SpVgg Greuther Fürth | - | 1899 Hoffenheim | 0:3 | ||||
| 26. Round | 16/03/2013 | 1899 Hoffenheim | - | 1. FSV Mainz 05 | 0:0 | |
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| 27. Round | 30/03/2013 | FC Schalke 04 | - | 1899 Hoffenheim | 3:0 | ||||
| 29. Round | 13/04/2013 | VfL Wolfsburg | - | 1899 Hoffenheim | 2:2 | ||||
| 30. Round | 20/04/2013 | Bayer Leverkusen | - | 1899 Hoffenheim | 5:0 | ||||
| 34. Round | 18/05/2013 | Borussia Dortmund | - | 1899 Hoffenheim | 1:2 |
Germany