| 2. Round | 21/08/1965 | Borussia Dortmund | - | Borussia Neunkirchen | 1:0 | ||||
| 4. Round | 04/09/1965 | Bayern München | - | Borussia Neunkirchen | 6:0 | ||||
| 8. Round | 16/10/1965 | VfB Stuttgart | - | Borussia Neunkirchen | 2:0 | ||||
| 11. Round | 05/11/1965 | Borussia Neunkirchen | - | Werder Bremen | 1:2 | ||||
| 12. Round | 06/11/1965 | TSV 1860 München | - | Borussia Neunkirchen | 4:1 | ||||
| 13. Round | 20/11/1965 | Borussia Neunkirchen | - | Frankfurter SG Eintracht | 1:6 | ||||
| 22. Round | 12/02/1966 | 1. FC Nürnberg | - | Borussia Neunkirchen | 3:1 | ||||
| 26. Round | 19/03/1966 | Meidericher SV | - | Borussia Neunkirchen | 1:0 | ||||
| 34. Round | 28/05/1966 | Borussia Neunkirchen | - | Karlsruher SC | 1:0 |
Germany