| 1. Round | 13/08/2000 | KRC Harelbeke | - | Standard Liège | 3:4 | ||||
| 6. Round | 16/09/2000 | Standard Liège | - | K.S.C. Eendracht Aalst | 7:0 |  |
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| 8. Round | 30/09/2000 | Standard Liège | - | KVC Westerlo | 5:3 | ||||
| 10. Round | 20/10/2000 | Standard Liège | - | RSC Charleroi | 4:0 | ||||
| 12. Round | 12/11/2000 | Standard Liège | - | RSC Anderlecht | 1:1 | ||||
| 13. Round | 18/11/2000 | Lierse SK (old) | - | Standard Liège | 1:1 | |
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| 14. Round | 24/11/2000 | Standard Liège | - | KRC Genk | 2:1 | ||||
| 21. Round | 04/02/2001 | Club Brugge KV | - | Standard Liège | 1:1 | ||||
| 30. Round | 21/04/2001 | Standard Liège | - | Lierse SK (old) | 3:2 | ||||
| 32. Round | 05/05/2001 | Standard Liège | - | KAA Gent | 1:0 | ||||
| 33. Round | 12/05/2001 | Excelsior Mouscron | - | Standard Liège | 1:1 | |
Czech Republic