| 7. Round | 20/10/2024 | Holstein Kiel | - | 1. FC Union Berlin | 0:2 | ||||
| 8. Round | 27/10/2024 | 1. FC Union Berlin | - | Eintracht Frankfurt | 1:1 | ||||
| 10. Round | 08/11/2024 | 1. FC Union Berlin | - | SC Freiburg | 0:0 | ||||
| 11. Round | 23/11/2024 | VfL Wolfsburg | - | 1. FC Union Berlin | 1:0 | ||||
| 12. Round | 30/11/2024 | 1. FC Union Berlin | - | Bayer Leverkusen | 1:2 |  |
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| 13. Round | 06/12/2024 | VfB Stuttgart | - | 1. FC Union Berlin | 3:2 |  |
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| 14. Round | 14/12/2024 | 1. FC Union Berlin | - | VfL Bochum | 0:2 dec. | ||||
| 15. Round | 21/12/2024 | Werder Bremen | - | 1. FC Union Berlin | 4:1 | ||||
| 16. Round | 11/01/2025 | 1. FC Heidenheim 1846 | - | 1. FC Union Berlin | 2:0 | ||||
| 17. Round | 15/01/2025 | 1. FC Union Berlin | - | FC Augsburg | 0:2 | ||||
| 18. Round | 19/01/2025 | 1. FC Union Berlin | - | 1. FSV Mainz 05 | 2:1 | |
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| 19. Round | 26/01/2025 | FC St. Pauli | - | 1. FC Union Berlin | 3:0 | ||||
| 20. Round | 01/02/2025 | 1. FC Union Berlin | - | RB Leipzig | 0:0 | ||||
| 21. Round | 08/02/2025 | 1899 Hoffenheim | - | 1. FC Union Berlin | 0:4 | ||||
| 22. Round | 15/02/2025 | 1. FC Union Berlin | - | Bor. Mönchengladbach | 1:2 |
Spain