| 1. Round | 20/08/1994 | Bayer 05 Uerdingen | - | MSV Duisburg | 1:1 | ||||
| 2. Round | 24/08/1994 | MSV Duisburg | - | FC Schalke 04 | 2:2 | ||||
| 3. Round | 27/08/1994 | Karlsruher SC | - | MSV Duisburg | 4:1 | ||||
| 4. Round | 02/09/1994 | MSV Duisburg | - | Bayern München | 0:3 | ||||
| 5. Round | 17/09/1994 | Dynamo Dresden | - | MSV Duisburg | 4:2 | ||||
| 6. Round | 23/09/1994 | MSV Duisburg | - | Werder Bremen | 0:2 | ||||
| 10. Round | 22/10/1994 | MSV Duisburg | - | Bayer Leverkusen | 0:2 | ||||
| 11. Round | 30/10/1994 | MSV Duisburg | - | Hamburger SV | 0:5 | ||||
| 12. Round | 05/11/1994 | TSV 1860 München | - | MSV Duisburg | 1:1 |  |
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| 20. Round | 03/03/1995 | MSV Duisburg | - | Karlsruher SC | 0:0 | ||||
| 26. Round | 15/04/1995 | MSV Duisburg | - | Bor. Mönchengladbach | 0:2 | ||||
| 27. Round | 22/04/1995 | Bayer Leverkusen | - | MSV Duisburg | 2:0 | |
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| 28. Round | 28/04/1995 | Hamburger SV | - | MSV Duisburg | 3:0 |
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