| 3. Round | 27/08/2022 | 1. FC Union Berlin [Youth B] | - | Hamburger SV [Youth B] | 1:3 |  |
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| 4. Round | 04/09/2022 | SV Meppen [Youth B] | - | 1. FC Union Berlin [Youth B] | 0:4 | ||||
| 5. Round | 24/09/2022 | 1. FC Union Berlin [Youth B] | - | Erzgebirge Aue [Youth B] | 1:1 | |
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| 8. Round | 22/10/2022 | Niendorfer TSV [Youth B] | - | 1. FC Union Berlin [Youth B] | 2:4 | |
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| 9. Round | 29/10/2022 | 1. FC Union Berlin [Youth B] | - | VfL Wolfsburg [Youth B] | 1:2 | |
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| 10. Round | 05/11/2022 | RB Leipzig [Youth B] | - | 1. FC Union Berlin [Youth B] | 1:2 | ||||
| 11. Round | 12/11/2022 | 1. FC Union Berlin [Youth B] | - | Werder Bremen [Youth B] | 1:5 | ||||
| 15. Round | 26/02/2023 | 1. FC Union Berlin [Youth B] | - | Hannover 96 [Youth B] | 0:6 |
Germany
Italy