| 1. Round | 25/08/2012 | Bor. Mönchengladbach | - | 1899 Hoffenheim | 2:1 | ||||
| 8. Round | 19/10/2012 | 1899 Hoffenheim | - | SpVgg Greuther Fürth | 3:3 | ||||
| 10. Round | 03/11/2012 | 1899 Hoffenheim | - | FC Schalke 04 | 3:2 |  |
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| 12. Round | 18/11/2012 | 1899 Hoffenheim | - | VfL Wolfsburg | 1:3 | ||||
| 13. Round | 25/11/2012 | 1899 Hoffenheim | - | Bayer Leverkusen | 1:2 | ||||
| 14. Round | 28/11/2012 | 1. FC Nürnberg | - | 1899 Hoffenheim | 4:2 | |
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| 15. Round | 02/12/2012 | 1899 Hoffenheim | - | Werder Bremen | 1:4 |  |
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| 16. Round | 07/12/2012 | Hamburger SV | - | 1899 Hoffenheim | 2:0 | ||||
| 17. Round | 16/12/2012 | 1899 Hoffenheim | - | Borussia Dortmund | 1:3 | |
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| 27. Round | 30/03/2013 | FC Schalke 04 | - | 1899 Hoffenheim | 3:0 | ||||
| 28. Round | 05/04/2013 | 1899 Hoffenheim | - | Fortuna Düsseldorf | 3:0 | |
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| 29. Round | 13/04/2013 | VfL Wolfsburg | - | 1899 Hoffenheim | 2:2 | ||||
| 30. Round | 20/04/2013 | Bayer Leverkusen | - | 1899 Hoffenheim | 5:0 | ||||
| 32. Round | 04/05/2013 | Werder Bremen | - | 1899 Hoffenheim | 2:2 | |
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| 33. Round | 11/05/2013 | 1899 Hoffenheim | - | Hamburger SV | 1:4 | ||||
| 34. Round | 18/05/2013 | Borussia Dortmund | - | 1899 Hoffenheim | 1:2 | |
Germany