| 5. Round | 03/10/1999 | Sportfreunde Siegen [Women] | - | FSV Frankfurt [Women] | 3:0 |  |
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| 6. Round | 10/10/1999 | FFC Flaesheim-Hillen [Women] | - | Sportfreunde Siegen [Women] | 1:6 | |
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| 7. Round | 17/10/1999 | Sportfreunde Siegen [Women] | - | 1. FC Nürnberg [Women] | 4:0 | ||||
| 9. Round | 31/10/1999 | Sportfreunde Siegen [Women] | - | FCR Duisburg 55 [Women] | 0:6 | ||||
| 10. Round | 14/11/1999 | Sportfreunde Siegen [Women] | - | 1. FFC Frankfurt [Women] | 0:0 | ||||
| 11. Round | 20/11/1999 | 1. FC Saarbrücken [Women] | - | Sportfreunde Siegen [Women] | 0:0 | ||||
| 12. Round | 05/12/1999 | WSV Wolfsburg-Wendschott [Women] | - | Sportfreunde Siegen [Women] | 3:2 |
Germany