| 5. Round | 14/09/2013 | 1. FSV Mainz 05 [Youth] | - | Eintracht Frankfurt [Youth] | 0:3 | ||||
| 6. Round | 22/09/2013 | Karlsruher SC [Youth] | - | 1. FSV Mainz 05 [Youth] | 0:1 | ||||
| 8. Round | 19/10/2013 | SpVgg Greuther Fürth [Youth] | - | 1. FSV Mainz 05 [Youth] | 1:4 |  |
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| 9. Round | 27/10/2013 | 1. FSV Mainz 05 [Youth] | - | Wacker Burghausen [Youth] | 2:0 | ||||
| 10. Round | 02/11/2013 | Bayern München [Youth] | - | 1. FSV Mainz 05 [Youth] | 0:2 | ||||
| 11. Round | 10/11/2013 | 1. FSV Mainz 05 [Youth] | - | TSV 1860 München [Youth] | 3:0 |  |
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| 12. Round | 23/11/2013 | 1. FSV Mainz 05 [Youth] | - | FC-Astoria Walldorf [Youth] | 2:2 | ||||
| 13. Round | 01/12/2013 | 1. FC Kaiserslautern [Youth] | - | 1. FSV Mainz 05 [Youth] | 0:0 | ||||
| 14. Round | 07/12/2013 | 1899 Hoffenheim [Youth] | - | 1. FSV Mainz 05 [Youth] | 1:1 | ||||
| 17. Round | 23/02/2014 | 1. FSV Mainz 05 [Youth] | - | FC Augsburg [Youth] | 1:1 | ||||
| 20. Round | 23/03/2014 | SpVgg Unterhaching [Youth] | - | 1. FSV Mainz 05 [Youth] | 2:0 |
Germany