| 3. Round | 14/08/2022 | SG Mülheim-Kärlich | - | TSV Schott Mainz | 3:4 | ||||
| 4. Round | 20/08/2022 | TSV Schott Mainz | - | SV Alemannia Waldalgesheim | 7:0 |  |
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| 5. Round | 27/08/2022 | Ahrweiler BC | - | TSV Schott Mainz | 0:3 | ||||
| 14. Round | 29/10/2022 | TSV Schott Mainz | - | SG Mülheim-Kärlich | 2:0 | ||||
| 15. Round | 05/11/2022 | SV Alemannia Waldalgesheim | - | TSV Schott Mainz | 0:3 | ||||
| 16. Round | 12/11/2022 | TSV Schott Mainz | - | Ahrweiler BC | 4:1 | ||||
| 11. Round | 16/11/2022 | TSV Schott Mainz | - | FV Engers 07 | 2:4 | ||||
| 18. Round | 26/11/2022 | Sportfreunde Eisbachtal | - | TSV Schott Mainz | 1:4 | ||||
| 20. Round | 10/12/2022 | TuS Kirchberg | - | TSV Schott Mainz | 1:4 | ||||
| 22. Round | 04/03/2023 | FV Engers 07 | - | TSV Schott Mainz | 0:0 |
Germany