| 1. Round | 12/08/2006 | 1. FSV Mainz 05 | - | VfL Bochum | 2:1 |  |
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| 2. Round | 19/08/2006 | Borussia Dortmund | - | 1. FSV Mainz 05 | 1:1 | ||||
| 3. Round | 27/08/2006 | 1. FSV Mainz 05 | - | Eintracht Frankfurt | 1:1 | ||||
| 4. Round | 16/09/2006 | Energie Cottbus | - | 1. FSV Mainz 05 | 2:0 | ||||
| 5. Round | 23/09/2006 | 1. FSV Mainz 05 | - | Hertha BSC | 1:1 | ||||
| 6. Round | 30/09/2006 | 1. FC Nürnberg | - | 1. FSV Mainz 05 | 1:1 | ||||
| 8. Round | 21/10/2006 | Arminia Bielefeld | - | 1. FSV Mainz 05 | 1:0 | ||||
| 14. Round | 25/11/2006 | Hannover 96 | - | 1. FSV Mainz 05 | 1:0 |
Germany