| 1. Round | 28/07/1990 | Waldhof Mannheim | - | Blau-Weiß 90 Berlin | 2:0 | ||||
| 6. Round | 26/08/1990 | MSV Duisburg | - | Waldhof Mannheim | 1:1 | ||||
| 7. Round | 31/08/1990 | SV Meppen | - | Waldhof Mannheim | 0:0 | ||||
| 8. Round | 05/09/1990 | Waldhof Mannheim | - | FC Schalke 04 | 1:3 | ||||
| 10. Round | 15/09/1990 | Waldhof Mannheim | - | FC 08 Homburg | 1:1 | ||||
| 11. Round | 21/09/1990 | Preußen Münster | - | Waldhof Mannheim | 0:0 | ||||
| 12. Round | 29/09/1990 | Waldhof Mannheim | - | VfB Oldenburg | 2:1 | ||||
| 13. Round | 05/10/1990 | Hannover 96 | - | Waldhof Mannheim | 0:5 |  |
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| 14. Round | 13/10/1990 | Waldhof Mannheim | - | SC Freiburg | 3:1 | ||||
| 15. Round | 21/10/1990 | 1. FSV Mainz 05 | - | Waldhof Mannheim | 3:1 |  |
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| 16. Round | 27/10/1990 | Waldhof Mannheim | - | Fortuna Köln | 2:0 | ||||
| 17. Round | 09/11/1990 | Rot-Weiss Essen | - | Waldhof Mannheim | 1:1 | ||||
| 19. Round | 23/11/1990 | 1. FC Saarbrücken | - | Waldhof Mannheim | 0:0 | ||||
| 35. Round | 25/05/1991 | Fortuna Köln | - | Waldhof Mannheim | 1:0 |
Germany