| 1. Round | 30/07/2005 | FC Sochaux | - | Toulouse FC | 0:1 | ||||
| 2. Round | 06/08/2005 | Toulouse FC | - | OGC Nice | 0:2 | ||||
| 3. Round | 13/08/2005 | Paris Saint-Germain | - | Toulouse FC | 2:0 | ||||
| 4. Round | 21/08/2005 | Toulouse FC | - | AS Saint-Étienne | 1:1 | ||||
| 5. Round | 24/08/2005 | Lille OSC | - | Toulouse FC | 0:0 | ||||
| 6. Round | 10/09/2005 | Toulouse FC | - | Le Mans UC 72 | 0:2 | ||||
| 7. Round | 17/09/2005 | FC Nantes | - | Toulouse FC | 2:0 |  |
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| 9. Round | 24/09/2005 | RC Strasbourg | - | Toulouse FC | 2:4 | |
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| 19. Round | 18/12/2005 | AS Monaco | - | Toulouse FC | 1:0 |
France