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| 31/08/2019 | 10:00 | FK Pirmasens | - | VfL Bochum | 1:5 (0:1) | |
| 10:00 | Hallescher FC | - | FC St. Pauli | 0:1 (0:0) | ||
| 10:00 | SC Borgfeld | - | Bayer Leverkusen | 0:6 (0:2) | ||
| 10:00 | FC Ingolstadt 04 | - | SC Freiburg | 2:0 (2:0) | ||
| 10:00 | Kickers Offenbach | - | Bor. Mönchengladbach | 1:3 (0:2) | ||
| 10:00 | Hansa Rostock | - | Jahn Regensburg | 2:3 (2:3) | ||
| 10:00 | 1. FC Köln | - | 1. FSV Mainz 05 | 1:2 (0:2) | ||
| 10:00 | Fortuna Düsseldorf | - | Hannover 96 | 1:4 (1:1, 2:2, 2:2) pso | ||
| 10:00 | Borussia Dortmund | - | RB Leipzig | 1:2 (1:0) | ||
| 11:00 | SSV Ulm 1846 | - | 1899 Hoffenheim | 4:2 (0:0, 2:2) aet | ||
| 11:00 | Energie Cottbus | - | Hertha BSC | 3:2 (2:1) | ||
| 11:00 | Holstein Kiel | - | Werder Bremen | 1:2 (1:0) | ||
| 13:00 | SV 07 Elversberg | - | VfB Stuttgart | 0:3 (0:3) | ||
| 01/09/2019 | 09:00 | VfL Wolfsburg | - | Bayern München | 2:3 (2:0) | |
| 10:00 | Rot-Weiß Erfurt | - | FC Schalke 04 | 1:2 (1:2) | ||
| 10:00 | SG Mülheim-Kärlich | - | Dynamo Dresden | 0:9 (0:5) |
