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| 1st(1st leg) | Sporting CP | - | İstanbul Başakşehir | 3:1 (2:0) | ||
| 2nd (2nd leg) | İstanbul Başakşehir | - | Sporting CP | 4:1 (2:0, 3:1) aet | ||
| 1st(1st leg): 20/02/2020 17:55 | 2nd (2nd leg): 27/02/2020 17:55 | Winner: İstanbul Başakşehir | ||||
| 1st(1st leg) | Getafe CF | - | AFC Ajax | 2:0 (1:0) | ||
| 2nd (2nd leg) | AFC Ajax | - | Getafe CF | 2:1 (1:1) | ||
| 1st(1st leg): 20/02/2020 17:55 | 2nd (2nd leg): 27/02/2020 20:00 | Winner: Getafe CF | ||||
| 1st(1st leg) | FC København | - | Celtic FC | 1:1 (0:1) | ||
| 2nd (2nd leg) | Celtic FC | - | FC København | 1:3 (0:0) | ||
| 1st(1st leg): 20/02/2020 17:55 | 2nd (2nd leg): 27/02/2020 20:00 | Winner: FC København | ||||
| 1st(1st leg) | CFR Cluj | - | Sevilla FC | 1:1 (0:0) | ||
| 2nd (2nd leg) | Sevilla FC | - | CFR Cluj | 0:0 (0:0) | ||
| 1st(1st leg): 20/02/2020 17:55 | 2nd (2nd leg): 27/02/2020 20:00 | Winner: Sevilla FC | ||||
| 1st(1st leg) | Club Brugge KV | - | Manchester United | 1:1 (1:1) | ||
| 2nd (2nd leg) | Manchester United | - | Club Brugge KV | 5:0 (3:0) | ||
| 1st(1st leg): 20/02/2020 17:55 | 2nd (2nd leg): 27/02/2020 20:00 | Winner: Manchester United | ||||
| 1st(1st leg) | PFC Ludogorets Razgrad | - | Inter | 0:2 (0:0) | ||
| 2nd (2nd leg) | Inter | - | PFC Ludogorets Razgrad | 2:1 (2:1) | ||
| 1st(1st leg): 20/02/2020 17:55 | 2nd (2nd leg): 27/02/2020 20:00 | Winner: Inter | ||||
| 1st(1st leg) | Eintracht Frankfurt | - | RB Salzburg | 4:1 (2:0) | ||
| 2nd (2nd leg) | RB Salzburg | - | Eintracht Frankfurt | 2:2 (1:1) | ||
| 1st(1st leg): 20/02/2020 17:55 | 2nd (2nd leg): 28/02/2020 17:00 | Winner: Eintracht Frankfurt | ||||
| 1st(1st leg) | Shakhtar Donetsk | - | SL Benfica | 2:1 (0:0) | ||
| 2nd (2nd leg) | SL Benfica | - | Shakhtar Donetsk | 3:3 (2:1) | ||
| 1st(1st leg): 20/02/2020 17:55 | 2nd (2nd leg): 27/02/2020 20:00 | Winner: Shakhtar Donetsk | ||||
| 1st(1st leg) | Wolverhampton Wanderers | - | Espanyol Barcelona | 4:0 (1:0) | ||
| 2nd (2nd leg) | Espanyol Barcelona | - | Wolverhampton Wanderers | 3:2 (1:1) | ||
| 1st(1st leg): 20/02/2020 20:00 | 2nd (2nd leg): 27/02/2020 17:55 | Winner: Wolverhampton Wanderers | ||||
| 1st(1st leg) | Bayer Leverkusen | - | FC Porto | 2:1 (1:0) | ||
| 2nd (2nd leg) | FC Porto | - | Bayer Leverkusen | 1:3 (0:1) | ||
| 1st(1st leg): 20/02/2020 20:00 | 2nd (2nd leg): 27/02/2020 17:55 | Winner: Bayer Leverkusen | ||||
| 1st(1st leg) | APOEL Nikosia | - | FC Basel 1893 | 0:3 (0:1) | ||
| 2nd (2nd leg) | FC Basel 1893 | - | APOEL Nikosia | 1:0 (1:0) | ||
| 1st(1st leg): 20/02/2020 20:00 | 2nd (2nd leg): 27/02/2020 17:55 | Winner: FC Basel 1893 | ||||
| 1st(1st leg) | Olympiakos Piraeus | - | Arsenal FC | 0:1 (0:0) | ||
| 2nd (2nd leg) | Arsenal FC | - | Olympiakos Piraeus | 1:2 (0:0, 0:1) aet | ||
| 1st(1st leg): 20/02/2020 20:00 | 2nd (2nd leg): 27/02/2020 20:00 | Winner: Olympiakos Piraeus | ||||
| 1st(1st leg) | AZ Alkmaar | - | LASK | 1:1 (0:1) | ||
| 2nd (2nd leg) | LASK | - | AZ Alkmaar | 2:0 (1:0) | ||
| 1st(1st leg): 20/02/2020 20:00 | 2nd (2nd leg): 27/02/2020 17:55 | Winner: LASK | ||||
| 1st(1st leg) | VfL Wolfsburg | - | Malmö FF | 2:1 (0:0) | ||
| 2nd (2nd leg) | Malmö FF | - | VfL Wolfsburg | 0:3 (0:1) | ||
| 1st(1st leg): 20/02/2020 20:00 | 2nd (2nd leg): 27/02/2020 17:55 | Winner: VfL Wolfsburg | ||||
| 1st(1st leg) | AS Roma | - | KAA Gent | 1:0 (1:0) | ||
| 2nd (2nd leg) | KAA Gent | - | AS Roma | 1:1 (1:1) | ||
| 1st(1st leg): 20/02/2020 20:00 | 2nd (2nd leg): 27/02/2020 17:55 | Winner: AS Roma | ||||
| 1st(1st leg) | Rangers FC | - | Sporting Braga | 3:2 (0:1) | ||
| 2nd (2nd leg) | Sporting Braga | - | Rangers FC | 0:1 (0:0) | ||
| 1st(1st leg): 20/02/2020 20:00 | 2nd (2nd leg): 26/02/2020 17:00 | Winner: Rangers FC | ||||
