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| 1st(1st leg) | KFC Uerdingen 05 | - | Altona 93 | 2:0 | ||
| 2nd (2nd leg) | Altona 93 | - | KFC Uerdingen 05 | 0:4 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: KFC Uerdingen 05 | ||||
| 1st(1st leg) | 1. FC Saarbrücken | - | SC Freiburg | 3:3 | ||
| 2nd (2nd leg) | SC Freiburg | - | 1. FC Saarbrücken | 1:0 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: SC Freiburg | ||||
| 1st(1st leg) | Bayer Leverkusen | - | VfB Kiel | 4:0 | ||
| 2nd (2nd leg) | VfB Kiel | - | Bayer Leverkusen | 1:2 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: Bayer Leverkusen | ||||
| 1st(1st leg) | VfB Stuttgart | - | Bayern München | 3:1 | ||
| 2nd (2nd leg) | Bayern München | - | VfB Stuttgart | 2:4 pso | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: VfB Stuttgart | ||||
| 1st(1st leg) | Kickers Offenbach | - | Eintracht Braunschweig | 2:2 | ||
| 2nd (2nd leg) | Eintracht Braunschweig | - | Kickers Offenbach | 3:1 pso | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: Eintracht Braunschweig | ||||
| 1st(1st leg) | VfL Bochum | - | SC Siemensstadt | 1:2 | ||
| 2nd (2nd leg) | SC Siemensstadt | - | VfL Bochum | 4:3 pso | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: SC Siemensstadt | ||||
| 1st(1st leg) | Werder Bremen | - | SV Schwetzingen | 2:1 | ||
| 2nd (2nd leg) | SV Schwetzingen | - | Werder Bremen | 3:0 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: SV Schwetzingen | ||||
| 1st(1st leg) | EGC Wirges | - | 1. FC Kaiserslautern | 1:3 | ||
| 2nd (2nd leg) | 1. FC Kaiserslautern | - | EGC Wirges | 5:1 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: 1. FC Kaiserslautern | ||||
