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| 1st(1st leg) | 1. FC Phönix Lübeck | - | Hamburger SV | 0:2 | ||
| 2nd (2nd leg) | Hamburger SV | - | 1. FC Phönix Lübeck | 1:1 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: Hamburger SV | ||||
| 1st(1st leg) | Werder Bremen | - | FC Schalke 04 | 2:0 | ||
| 2nd (2nd leg) | FC Schalke 04 | - | Werder Bremen | 3:0 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: FC Schalke 04 | ||||
| 1st(1st leg) | Hertha BSC | - | Hannover 96 | 5:0 | ||
| 2nd (2nd leg) | Hannover 96 | - | Hertha BSC | 4:5 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: Hertha BSC | ||||
| 1st(1st leg) | 1. FC Köln | - | KFC Uerdingen 05 | 1:2 | ||
| 2nd (2nd leg) | KFC Uerdingen 05 | - | 1. FC Köln | 2:1 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: KFC Uerdingen 05 | ||||
| 1st(1st leg) | Eintracht Frankfurt | - | 1. FC Nürnberg | 5:2 | ||
| 2nd (2nd leg) | 1. FC Nürnberg | - | Eintracht Frankfurt | 2:5 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: Eintracht Frankfurt | ||||
| 1st(1st leg) | Karlsruher SC | - | TuS Koblenz | 6:0 | ||
| 2nd (2nd leg) | TuS Koblenz | - | Karlsruher SC | 1:1 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: Karlsruher SC | ||||
| 1st(1st leg) | SC Freiburg | - | FC 08 Homburg | 1:1 | ||
| 2nd (2nd leg) | FC 08 Homburg | - | SC Freiburg | 0:3 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: SC Freiburg | ||||
| 1st(1st leg) | 1. FC Kaiserslautern | - | SSV Reutlingen | 1:0 | ||
| 2nd (2nd leg) | SSV Reutlingen | - | 1. FC Kaiserslautern | 0:3 | ||
| 1st(1st leg): 02/06/1991 | 2nd (2nd leg): 09/06/1991 | Winner: 1. FC Kaiserslautern | ||||
