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| 1st(1st leg) | 1. FSV Mainz 05 | - | 1. FC Köln | 1:0 (1:0) | ||
| 2nd (2nd leg) | 1. FC Köln | - | 1. FSV Mainz 05 | 0:0 (0:0) | ||
| 1st(1st leg): 09/04/2023 12:00 | 2nd (2nd leg): 14/04/2023 15:00 | Winner: 1. FSV Mainz 05 | ||||
| 1st(1st leg) | Hertha BSC | - | Borussia Dortmund | 0:4 (0:3) | ||
| 2nd (2nd leg) | Borussia Dortmund | - | Hertha BSC | 0:1 (0:1) | ||
| 1st(1st leg): 10/04/2023 10:00 | 2nd (2nd leg): 15/04/2023 10:00 | Winner: Borussia Dortmund | ||||
