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| 1st(1st leg) | RB Leipzig | - | Liverpool FC | 0:2 (0:0) | ||
| 2nd (2nd leg) | Liverpool FC | - | RB Leipzig | 2:0 (0:0) | ||
| 1st(1st leg): 16/02/2021 20:00 | 2nd (2nd leg): 10/03/2021 20:00 | Winner: Liverpool FC | ||||
| 1st(1st leg) | FC Barcelona | - | Paris Saint-Germain | 1:4 (1:1) | ||
| 2nd (2nd leg) | Paris Saint-Germain | - | FC Barcelona | 1:1 (1:1) | ||
| 1st(1st leg): 16/02/2021 20:00 | 2nd (2nd leg): 10/03/2021 20:00 | Winner: Paris Saint-Germain | ||||
| 1st(1st leg) | FC Porto | - | Juventus | 2:1 (1:0) | ||
| 2nd (2nd leg) | Juventus | - | FC Porto | 3:2 (0:1, 2:1) aet | ||
| 1st(1st leg): 17/02/2021 20:00 | 2nd (2nd leg): 09/03/2021 20:00 | Winner: FC Porto | ||||
| 1st(1st leg) | Sevilla FC | - | Borussia Dortmund | 2:3 (1:3) | ||
| 2nd (2nd leg) | Borussia Dortmund | - | Sevilla FC | 2:2 (1:0) | ||
| 1st(1st leg): 17/02/2021 20:00 | 2nd (2nd leg): 09/03/2021 20:00 | Winner: Borussia Dortmund | ||||
| 1st(1st leg) | Lazio Roma | - | Bayern München | 1:4 (0:3) | ||
| 2nd (2nd leg) | Bayern München | - | Lazio Roma | 2:1 (1:0) | ||
| 1st(1st leg): 23/02/2021 20:00 | 2nd (2nd leg): 17/03/2021 20:00 | Winner: Bayern München | ||||
| 1st(1st leg) | Atlético Madrid | - | Chelsea FC | 0:1 (0:0) | ||
| 2nd (2nd leg) | Chelsea FC | - | Atlético Madrid | 2:0 (1:0) | ||
| 1st(1st leg): 23/02/2021 20:00 | 2nd (2nd leg): 17/03/2021 20:00 | Winner: Chelsea FC | ||||
| 1st(1st leg) | Bor. Mönchengladbach | - | Manchester City | 0:2 (0:1) | ||
| 2nd (2nd leg) | Manchester City | - | Bor. Mönchengladbach | 2:0 (2:0) | ||
| 1st(1st leg): 24/02/2021 20:00 | 2nd (2nd leg): 16/03/2021 20:00 | Winner: Manchester City | ||||
| 1st(1st leg) | Atalanta | - | Real Madrid | 0:1 (0:0) | ||
| 2nd (2nd leg) | Real Madrid | - | Atalanta | 3:1 (1:0) | ||
| 1st(1st leg): 24/02/2021 20:00 | 2nd (2nd leg): 16/03/2021 20:00 | Winner: Real Madrid | ||||
