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| 1st(1st leg) | Borussia Dortmund | - | Paris Saint-Germain | 2:1 (0:0) | ||
| 2nd (2nd leg) | Paris Saint-Germain | - | Borussia Dortmund | 2:0 (2:0) | ||
| 1st(1st leg): 18/02/2020 20:00 | 2nd (2nd leg): 11/03/2020 20:00 | Winner: Paris Saint-Germain | ||||
| 1st(1st leg) | Atlético Madrid | - | Liverpool FC | 1:0 (1:0) | ||
| 2nd (2nd leg) | Liverpool FC | - | Atlético Madrid | 2:3 (1:0, 1:0) aet | ||
| 1st(1st leg): 18/02/2020 20:00 | 2nd (2nd leg): 11/03/2020 20:00 | Winner: Atlético Madrid | ||||
| 1st(1st leg) | Atalanta | - | Valencia CF | 4:1 (2:0) | ||
| 2nd (2nd leg) | Valencia CF | - | Atalanta | 3:4 (1:2) | ||
| 1st(1st leg): 19/02/2020 20:00 | 2nd (2nd leg): 10/03/2020 20:00 | Winner: Atalanta | ||||
| 1st(1st leg) | Tottenham Hotspur | - | RB Leipzig | 0:1 (0:0) | ||
| 2nd (2nd leg) | RB Leipzig | - | Tottenham Hotspur | 3:0 (2:0) | ||
| 1st(1st leg): 19/02/2020 20:00 | 2nd (2nd leg): 10/03/2020 20:00 | Winner: RB Leipzig | ||||
| 1st(1st leg) | Chelsea FC | - | Bayern München | 0:3 (0:0) | ||
| 2nd (2nd leg) | Bayern München | - | Chelsea FC | 4:1 (2:1) | ||
| 1st(1st leg): 25/02/2020 20:00 | 2nd (2nd leg): 08/08/2020 20:00 | Winner: Bayern München | ||||
| 1st(1st leg) | SSC Napoli | - | FC Barcelona | 1:1 (1:0) | ||
| 2nd (2nd leg) | FC Barcelona | - | SSC Napoli | 3:1 (3:1) | ||
| 1st(1st leg): 25/02/2020 20:00 | 2nd (2nd leg): 08/08/2020 20:00 | Winner: FC Barcelona | ||||
| 1st(1st leg) | Real Madrid | - | Manchester City | 1:2 (0:0) | ||
| 2nd (2nd leg) | Manchester City | - | Real Madrid | 2:1 (1:1) | ||
| 1st(1st leg): 26/02/2020 20:00 | 2nd (2nd leg): 07/08/2020 20:00 | Winner: Manchester City | ||||
| 1st(1st leg) | Olympique Lyon | - | Juventus | 1:0 (1:0) | ||
| 2nd (2nd leg) | Juventus | - | Olympique Lyon | 2:1 (1:1) | ||
| 1st(1st leg): 26/02/2020 20:00 | 2nd (2nd leg): 07/08/2020 20:00 | Winner: Olympique Lyon | ||||
